cis-(Di-2-pyridylamine-kappa N-2(2),N-2')bis(thiocyanato-kappa S)platinum(II)

被引：0
|
作者：
Ha, Kwang [1 ]
机构：
[1] Chonnam Natl Univ, Res Inst Catalysis, Sch Appl Chem Engn, Kwangju 500757, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
基金：
新加坡国家研究基金会;
关键词：
D O I：
10.1107/S1600536812010926
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Pt(NCS)(2)(C10H9N3)],the Pt-II ion is four-coordinated in a distorted square-planar environment by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two mutually cis S atoms from two linear thiocyanate anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 30.8 (4)degrees. In the crystal, the complex molecules are stacked in columns along the a axis and are connected by intermolecular N-H center dot center dot center dot N hydrogen bonds, forming supramolecular chains along the b axis.
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页码：M440 / +
页数：7
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