Mass Spectrometric Indication of Double-bond Position in Dodecenyl Acetates Based on a Fuzzy Classification

被引:3
|
作者
Horiike, Michio [1 ]
Gu, Yuan [1 ]
Hirano, Chisato [1 ]
机构
[1] Kochi Univ, Dept Agr Chem, Nankoku, Kochi 783, Japan
关键词
D O I
10.1002/rcm.1290030403
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Ten positional isomers of dodecenyl acetate were analyzed by conventional combined gas chromatography/electron ionization mass spectrometry. The relative intensities of some predominant fragments in the isomers examined varied with the double-bond position in the chain. The mass spectra were interpreted in terms of the standard parameters, similarity coefficients, clustering weight and clustering coefficients. The original double-bond position in the acetates was located unambiguously.
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页码:100 / 101
页数:2
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