A PREDICATIVE MODEL FOR CERTAIN DIRECTED METALATIONS .3. THE ABILITY OF A METHYL SUBSTITUENT TO INFLUENCE THE DIRECTED METALATION OF ANISOLE

被引：2
|
作者：
SLOCUM, DW
THOMPSON, J
FRIESEN, C
机构：
[1] Department of Chemistry, Western Kentucky University, Bowling Green
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 45期
关键词：
D O I：
10.1016/0040-4039(95)01764-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Significant increases in both rate and yield of metalation of p-methylanisole (p-MA) are afforded by use of incremental and stoichiometric amounts of TMEDA. Little metalation of the methyl protons in p-MA is observed under all conditions.
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页码：8171 / 8174
页数：4
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