TRANSITION-METAL OXIDES AS CATALYSTS FOR THE SELECTIVE REDUCTION OF NITROBENZENE

被引：11
|
作者：
MALTHA, A [1 ]
VANWERMESKERKEN, SC [1 ]
BRUNET, B [1 ]
PONEC, V [1 ]
机构：
[1] LEIDEN UNIV,LEIDEN INST CHEM,GORLAEUS LABS,2300 RA LEIDEN,NETHERLANDS
来源：
JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 93卷 / 03期
关键词：
BOND STRENGTH; METAL-OXYGEN BOND; NITROBENZENE; SELECTIVE REDUCTION; TRANSITION METAL OXIDES;
D O I：
10.1016/0304-5102(94)00121-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The activity of various 3d, 4d and 5d transition metal oxides in the selective reduction of nitrobenzene to nitrosobenzene has been investigated. An attempt has been made to find a correlation between these activities and several properties of the oxides investigated, such as their place in the Periodic Table, structure, reducibility, heat of formation and surface metal-oxygen bond strength. A weak volcano-shape correlation can be seen with the heat of formation and the surface metal-oxygen bond strength.
引用
收藏
页码：305 / 316
页数：12
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