SYNTHESIS OF OLIGO(1,4-PHENYLENEVINYLENE) AND POLY(1,4-PHENYLENEVINYLENE) BY METATHETIC POLYCONDENSATION OF 1,4-DIVINYLBENZENE

被引：11
|
作者：
THORNCSANYI, E
PFLUG, KP
机构：
[1] Institut für Technische und Makromolekulare Chemie, Universität Hamburg, D-20146 Hamburg
来源：
JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 90卷 / 1-2期
关键词：
CARBENES; 1,4-DIVINYLBENZENE; METATHESIS; PHENYLENEVINYLENE UNITS; POLYCONDENSATION; TUNGSTEN;
D O I：
10.1016/0304-5102(93)E0305-Z
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The monomer 1,4-divinylbenzene (DVB) is directly polymerizable via metathetic polycondensation with the well-defined tungsten carbene [W(CHAr') (NAr) [OCMe(CF3)2]2(THF)] (Ar = 2,6-Me2C6H3, Ar'= o-MeOC6H4) to DVB oligomers and poly(1,4-phenylenevinylene) (PPV). The sequence length of the 1,4-phenylenevinylene units depends on the employed reaction parameters.
引用
收藏
页码：69 / 74
页数：6
相关论文
共 50 条
  • [1] SPECTROSCOPIC PROPERTIES OF POLY(1,4-PHENYLENEVINYLENE) AND POLY(2-METHOXY-1,4-PHENYLENEVINYLENE)
    LEE, GJ
    YU, SK
    KIM, D
    LEE, JI
    SHIM, HK
    [J]. SYNTHETIC METALS, 1995, 69 (1-3) : 431 - 432
  • [2] SYNTHESIS OF POLY(1,4-PHENYLENEVINYLENE) BY METATHESIS OF PARA-DIVINYLBENZENE
    KUMAR, A
    EICHINGER, BE
    [J]. MAKROMOLEKULARE CHEMIE-RAPID COMMUNICATIONS, 1992, 13 (06): : 311 - 314
  • [3] Synthesis and characterization of poly(2,5-dipropargyloxy-1,4-phenylenevinylene) and its copolymers with 1,4-phenylenevinylene
    Shim, HK
    Hwang, DH
    Yoon, CB
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (08) : 2393 - 2401
  • [4] PALLADIUM CATALYZED SYNTHESIS OF POLY(1,4-PHENYLENEVINYLENE)
    GREINER, A
    MARTELOCK, H
    HEITZ, W
    [J]. SYNTHETIC METALS, 1991, 41 (03) : 881 - 884
  • [5] SYNTHESIS AND CHARACTERIZATION OF POLY(1,4-PHENYLENEVINYLENE) DERIVATIVES
    KAUL, SN
    FERNANDEZ, JE
    [J]. MACROMOLECULES, 1990, 23 (11) : 2875 - 2879
  • [6] Light emitting properties of poly(2-fluoro-1,4-phenylenevinylene) as compared with poly(1,4-phenylenevinylene)
    Shim, HK
    Lee, JI
    Kang, IN
    Jeoung, SC
    Kim, D
    Zyung, T
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1997, 294 : 117 - 122
  • [7] Tris[oligo(1,4-phenylenevinylene)]methylium Dyes
    Kim, Soungkyoo
    Kalbitz, Helga
    Hillmann, Sabine
    Meier, Herbert
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2009, 2009 (12) : 1976 - 1983
  • [8] PREPARATION AND PROPERTIES OF POLY(1,4-PHENYLENEVINYLENE) DERIVATIVES
    SONODA, Y
    NAKAO, Y
    KAERIYAMA, K
    [J]. SYNTHETIC METALS, 1993, 55 (2-3) : 918 - 923
  • [9] SYNTHESIS AND CHARACTERIZATION OF POLY(2-METHOXY-5-NITRO-1,4-PHENYLENEVINYLENE) AND POLY(1,4-PHENYLENEVINYLENE-CO-2-METHOXY-5-NITRO-1,4-PHENYLENEVINYLENE)S
    JIN, JI
    LEE, YH
    SHIM, HK
    [J]. MACROMOLECULES, 1993, 26 (08) : 1805 - 1810
  • [10] SYNTHESIS AND ELECTRICAL-CONDUCTIVITY OF POLY(1,4-PHENYLENEVINYLENE-CO-2-NITRO-1,4-PHENYLENEVINYLENE)
    JIN, JI
    YU, SH
    SHIM, HK
    [J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1993, 31 (01) : 87 - 92
12345