SOLVATION DYNAMICS IN ELECTROLYTE-SOLUTIONS

被引：42
|
作者：
CHANDRA, A
PATEY, GN
机构：
[1] Department of Chemistry, University of British Columbia, Vancouver
来源：
JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 02期
关键词：
D O I：
10.1063/1.466634
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A microscopic theory of the dynamics of ion solvation in electrolyte solutions is given. Consistent with the pure solvent case, the theory predicts a very fast and important inertial relaxation at short times. This is followed by oscillations and an extremely slow long-time decay associated with the formation of an equilibrium ''ion atmosphere'' about the newly charged particle.
引用
收藏
页码：1552 / 1558
页数：7
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