CHARGE-TRANSFER SPECTRA OF PERMETHYLATED POLYGERMANES TCNE TO AFFORD 1-1 ADDUCTS

被引:44
|
作者
MOCHIDA, K [1 ]
HODOTA, C [1 ]
HATA, R [1 ]
FUKUZUMI, S [1 ]
机构
[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN
关键词
D O I
10.1021/om00026a052
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Charge-transfer spectra of permethylated polygermane-tetracyanoethylene (TCNE) complexes were observed. The frequency of charge-transfer spectra was linearly related to ionization potentials (or electrochemical oxidation potentials) of the polygermanes. Polygermanes inserted into TCNE to afford 1:1 adducts under mild conditions.
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页码:586 / 588
页数:3
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