An unknown solvate of 1-(2,4-dichlorobenzyl)-4-[(4-methylphenyl)sulfonyl]piperazine

被引:1
|
作者
Sreenivasa, S. [1 ]
ManojKumar, K. E. [1 ]
Anitha, H. C. [2 ]
Suchetan, P. A.
Palakshamurthy, B. S. [3 ]
Jayashree, Yenagi [4 ]
Tonannavar, J. [4 ]
机构
[1] Tumkur Univ, Dept Studies & Res Chem, Tumkur 572103, Karnataka, India
[2] Tumkur Univ, Ctr Adv Mat, Dept Chem, Tumkur 572103, Karnataka, India
[3] Tumkur Univ, UCS, Dept Studies & Res Chem, Tumkur 572103, Karnataka, India
[4] Karnatak Univ, Dept Phys, Dharwad 580003, Karnataka, India
关键词
D O I
10.1107/S160053681301012X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C18H20Cl2N2O2S, the piperazine ring adopts a chair conformation. The dihedral angle between the sulfonyl-bound benzene ring and the best-fit plane through the six non-H atoms of the piperazine ring is 72.22 (12)degrees; those between the di-chloro-benzene ring and the sulfonyl and piperazine rings are 2.44 (13) and 74.16 (2)degrees, respectively. In the crystal, mol-ecules are connected through weak C-H center dot center dot center dot O inter-actions into a hexa-meric unit generating a R-6(6)(60) motif in the ab plane. The mol-ecules are also connected into C(4) chains through weak C-H center dot center dot center dot N inter-actions. The solvent used to grow the crystal was a mixture of di-chloro-methane and methanol, but the resulting electron density was uninter-pretable. The solvent contribution to the scattering was removed with the SQUEEZE routine in PLATON [Spek (2009 ?). Acta Cryst. D65, 148-155]. The formula mass and unit-cell characteristics do not take into account the disordered solvent.
引用
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页码:O782 / +
页数:9
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