SEQUENTIAL SIMPLEX OPTIMIZATION IN A CONSTRAINED SIMPLEX MIXTURE SPACE IN LIQUID-CHROMATOGRAPHY

被引：12
|
作者：
PALASOTA, JA [1 ]
LEONIDOU, I [1 ]
PALASOTA, JM [1 ]
CHANG, HL [1 ]
DEMING, SN [1 ]
机构：
[1] UNIV HOUSTON,DEPT CHEM,4800 CALHOUN RD,HOUSTON,TX 77204
来源：
ANALYTICA CHIMICA ACTA | 1992年 / 270卷 / 01期
关键词：
LIQUID CHROMATOGRAPHY; OPTIMIZATION METHODS; DESIRABILITY FUNCTIONS; ORGANIC SOLUTES; SEQUENTIAL SIMPLEX OPTIMIZATION;
D O I：
10.1016/0003-2670(92)80096-P
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The sequential simplex method is used in a constrained simplex mixture space to optimize the liquid chromatographic separation of five neutral organic solutes: uracil, phenol, acetophenone, methylbenzoate, and toluene. The mobile phase composition is varied while column temperature, mobile phase flow-rate, and sample concentration are held constant. The chromatographic response function and the total analysis time are used in an overall desirability function to direct the progress of the sequential simplex optimization.
引用
收藏
页码：101 / 106
页数：6
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