CRYSTAL-STRUCTURE OF BA5SIO4CL6

被引：10
|
作者：
ABED, M
MULLERBUSCHBAUM, H
机构：
[1] Institut für Anorganische Chemie der Christian-Albrechts-Universität, Olshausenstr. 40-60
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 1992年 / 190卷 / 01期
关键词：
D O I：
10.1016/0925-8388(92)90174-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Single crystals of Ba5SiO4Cl6 were prepared by a long-time flux technique. It crystallizes with monoclinic symmetry, space group C2h6-C2/c (a = 9.469 angstrom, b = 14.752 angstrom, c = 11.732 angstrom, beta = 104.58-degrees). The so far unknown crystal structure shows the expected SiO4 tetrahedra within a Ba2+/O2-/Cl- network. The coordination of the different point positions of Ba2+ will be discussed.
引用
收藏
页码：61 / 64
页数：4
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