MEASUREMENT MODELS FOR ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY .1. DEMONSTRATION OF APPLICABILITY

Use of measurement models is suggested as an intermediate step in the analysis of impedance data. In a manner analogous to the routine use of measurement models in the deconvolution of optical spectra, the measurement model could be used to guide development of physicoelectrochemical models by determining whether a data set is consistent with the Kramers-Kronig relations, by suggesting a form for the error structure of the data, and by providing an indication of the number and type of physical processes that can be resolved from the data. In this paper, a general measurement model is shown to apply for a wide variety of typical electrochemical impedance spectra. The application of the measurement models as a data filter will be addressed in subsequent papers.