ON THE UTILITY OF ALPHA-HETEROATOM SUBSTITUTED ORTHOESTERS IN THE JOHNSON-CLAISEN REARRANGEMENT

被引：7
|
作者：
ELWORTHY, TR [1 ]
MORGANS, DJ [1 ]
PALMER, WS [1 ]
REPKE, DB [1 ]
SMITH, DB [1 ]
WALTOS, AM [1 ]
机构：
[1] SYNTEX INC,DISCOVERY RES,INST ORGAN CHEM,PALO ALTO,CA 94304
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 28期
关键词：
D O I：
10.1016/S0040-4039(00)73290-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
alpha-Heteroatom substituted orthoesters were prepared and found to undergo the Johnson Claisen rearrangement with a variety of allylic alcohols giving gamma,delta-unsaturated alpha-heteroatom substituted esters in fair to excellent yields. The diastereoselectivity of the process was examined.
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收藏
页码：4951 / 4954
页数：4
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