ALKYLATION OF CYCLODODECANONE WITH ALPHA,OMEGA-DIBROMOALKANES UNDER CONDITIONS OF PHASE-TRANSFER CATALYSIS

被引：1
|
作者：
ZAKHARKIN, LI
CHURILOVA, IM
ANTONOVA, GN
PETROVSKII, PV
IKONNIKOV, NS
机构：
[1] A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 117813
来源：
RUSSIAN CHEMICAL BULLETIN | 1994年 / 43卷 / 08期
关键词：
ALKYLATION; ALPHA; OMEGA-DIBROMOALKANES; PHASE-TRANSFER CATALYSIS; CYCLODODECANONE; BICYCLO[9.3.0]PENTADECAN-15-ONE; BICYCLO[9.4.1]HEXADECAN-16-ONE; BICYCLO[9.5.1]HEPTADECAN-17-ONE; 2-ALLYL-; 2-(3-BROMOPROPYL)-; 2-(5-BROMOPENTYL)-; 2-METHYLENECYCLODODECANONE; 7-OXOSPIRO[4.11]HEXADECANE; 7-OXOSPIRO[5.11]HEPTADEC-2-ENE; 7-OXOSPIRO[5.11]HEPTADECANE;
D O I：
10.1007/BF00703694
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Alkylation of cyclododecanone with alpha,omega-dibromoalkanes Br(CH)(n)Br (n = 3, 4, 5) under conditions of phase-transfer catalysis in the presence of KOH results in the formation of either bicyclic ketones for n = 3 and 5 or a mixture of bicyclic and spirocyclic ketones for n = 4.
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页码：1360 / 1362
页数：3
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