CONTROLLED SYNTHESIS OF ORGANIC SUPERCONDUCTORS AND CONDUCTORS OF THE (BEDT-TTF)4HG3-DELTA-X8 COMPOSITION (X = CL, BR, I)

被引：5
|
作者：
LYUBOVSKAYA, RN
ALDOSHINA, MZ
GOLDENBERG, LM
ZHILYAEVA, EI
机构：
[1] USSR Academy, Sciences Institute of Chemical Physics, Chernogolovka
来源：
SYNTHETIC METALS | 1991年 / 42卷 / 1-2期
关键词：
Organometallics--Superconductivity;
D O I：
10.1016/0379-6779(91)92037-I
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The problem of controlled synthesis of cation-radical salts of bis(ethylenedithio)tetrathiafulvalene with halide-mercurate anions of the (BEDT-TTF) 4Hg3-delta-X8 composition (X = Cl, Br, I) is discussed. Compounds with X = Cl, Br are organic superconductors with T(c) = 1.8 K at 12 kbar for X = Cl and T(c) = 4.3 K at ambient pressure for X = = Br. The compound with X = I is an organic semiconductor.
引用
收藏
页码：2143 / 2146
页数：4
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