FECL3 BEHAVIOR IN ACETONITRILE - STRUCTURES OF [FECL2(CH3CN)4][FECL4] AND [ALCL(CH3CN)5][FECL4]2.CH3CN

被引：17
|
作者：
GAO, Y
GUERY, J
JACOBONI, C
机构：
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷
关键词：
D O I：
10.1107/S0108270192009892
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structures of the complexes [FeCl2(CH3CN)4]-[FeCl4], tetrakis(acetonitrile)dichloroiron(III) tetrachloroferrate(1-), and [AICI(CH3CN)5][FeCl4]2.-CH3CN, pentakis(acetonitrile)chloroaluminium(III) bis-[tetrachloroferrate(1-)] acetonitrile solvate, have been determined from single-crystal X-ray diffraction data. [FeCl2(CH3CN)4][FeCl4] is built up from [FeCl2-(CH3CN)4]+ octahedra and [FeCl4]- tetrahedra whereas [AlCI(CH3CN)5][FeCl4]2.CH3CN is composed of [AlCI-(CH3CN)5]2+ octahedra, [FeCl4]- tetrahedra and uncoordinated CH3CN molecules.
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页码：147 / 151
页数：5
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