PHASE EQUILIBRIUM IN THE SYSTEMS Cs2MoO4-R-2(MoO4)(3)-Hf(MoO4)(2) (R = Al, Cr, Fe, Bi, La-Lu)

被引：5
|
作者：
Bazarova, J. G. [1 ]
Tushinova, Yu L. [1 ]
Bazarov, B. G. [1 ]
Oyun, B. E. [2 ]
Angarhayev, J. D. [2 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Baikal Inst Nat Management, 6 Sakhyanovoi St, Ulan Ude 670047, Russia
[2] Buryat State Univ, 24 Smolina St, Ulan Ude 670000, Russia
来源：
IZVESTIYA VUZOV-PRIKLADNAYA KHIMIYA I BIOTEKHNOLOGIYA | 2018年 / 8卷 / 02期
关键词：
double and triple molibdates; lanthanides; cesium; phase equilibria; aluminum; chromium; iron;
D O I：
10.21285/2227-2925-2018-8-2-19-28
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
X-ray diffraction and differential scanning calorimetry methods are used to systematically study phase formation in the ternary salt systems Cs2MoO4-R-2(MoO4)(3)-Hf(MoO4)(2) (R-trivalent elements In systems, the formation of new triple molybdates of the compositions Cs5RHf(MoO4)(6) (R = Al, Cr, Fe, Bi) (S-1), Cs(RHf0,5)(MoO4)(3),(R = Al, Fe, Cr) (S-2), Cs2RBiHf2(MoO4)(6,5) (S-3) was detected. Taking into account the formation of new triple molybdates and the peculiarities of phase formation in facet systems, systems were triangulated in the subsolidus region. The thermal and electrophysical properties of synthesized compounds are determined. The triple molybdates Cs5RHf(MoO4)(6) (R = Al, Cr, Fe) are isostructural to the compound Rb5FeHf(MoO4)(6) (hexagonal symmetry, sp. gr. R. (3) over bar,, Z = 2), the isoformed bismuth analogue crystallizes in the trigonal system (Pr. R-3 = 3, Z = 6). The structural analog of Cs(RHf0.5)(MoO4)(3) (R = Al, Cr, Fe) is Cs(FeZr0.5)(MoO4)(3) (trigonal system, sp. gr. R-3, Z = 6). The identification of diffractograms and the determination of the crystallographic characteristics of the new molybdates of the lanthanide series Cs2RHf2(MoO4)(6.5) (R = Al, Cr, Fe, Bi, La-Lu) were carried out using the autoindication method with the TOPAS 4.2 software package.
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页码：19 / 28
页数：10
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