USEFUL AND ACCESSIBLE ORGANOMETALLIC PRECURSORS FOR PREPARATION OF ZINC-SULFIDE AND INDIUM SULFIDE THIN-FILMS VIA SOLUTION PYROLYSIS (PRINTING) METHOD

被引：16
|
作者：
NOMURA, R [1 ]
KONISHI, K [1 ]
FUTENMA, S [1 ]
MATSUDA, H [1 ]
机构：
[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 1990年 / 4卷 / 06期
关键词：
ORGANOZINC THIOLATES; ORGANOINDIUM THIOLATES; ZINC DITHIOCARBAMATES; ZINC SULFIDE THIN FILMS; INDIUM SULFIDE THIN FILMS; SOLUTION PYROLYSIS;
D O I：
10.1002/aoc.590040605
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Polycrystalline beta-zinc sulfide thin films were prepared by solution pyrolysis of an ethylzinc isopropylthiolate-zinc bis(dibutyldithiocarbamate) combined precursor (EtZnSiPr-Zn(S2CNnBu2)2) in chloroform solution on glass or silicon(111) substrates at 300-degrees-C. Homogeneous but amorphous indium sulfide thin films were obtained from butylindium bis(isopropylthiolate) (nBuInSiPr2) in p-xylene on these substrates at 300-degrees-C similarly. The sulfide thin films obtained were characterized by means of X-ray photoelectron spectroscopy (XPS), X-ray fluorescence microanalysis, scanning electron microscopy (SEM) and optical band gap measurements.
引用
收藏
页码：607 / 610
页数：4
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