4-Hydroxy-3-methoxybenzaldehyde 4-phenylthiosemicarbazone

被引：1
|
作者：
de Oliveira, Adriano Bof [1 ]
Santos Feitosa, Barbara Regina [1 ]
Naether, Christian [1 ]
Jess, Inke [1 ]
机构：
[1] Univ Fed Sergipe, Dept Quim, Av Marechal Rondon S-N Campus, BR-49100000 Sao Cristovao, SE, Brazil
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
Data-to-parameter ratio = 14.6; Mean σ(C-C) = 0.002 Å; R factor = 0.034; Single-crystal X-ray study; T = 200 K; wR factor = 0.083;
D O I：
10.1107/S1600536814002773
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C15H15N3O2S, the central C-N-N-C unit has an anti conformation [torsion angle = -170.17 (15)degrees]. The phenyl substituent is oriented perpendicular to this unit [dihedral angle of 89.2 (1)degrees], whereas the substituted ring is rotated out of this plane by only 18.86 (17)degrees. In the crystal, molecules are linked by pairs of N-H center dot center dot center dot S hydrogen bonds into inversion dimers that are further connected via NH center dot center dot center dot O and O-H center dot center dot center dot S hydrogen bonds into a three- dimensional network.
引用
收藏
页码：O278 / +
页数：7
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