THE REACTIVITY OF PD(PTBU3)2 TOWARDS THE OXONIUM ION - CRYSTAL-STRUCTURE OF TRANS-[(TBU3P)2PD(H)(CH3CN)]BPH4

被引：18
|
作者：
SOMMOVIGO, M
PASQUALI, M
LEONI, P
SABATINO, P
BRAGA, D
机构：
[1] DIPARTIMENTO CHIM G CIAMICIAN,VIA SELMI 2,I-40126 BOLOGNA,ITALY
[2] DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY
[3] SCUOLA NORMALE SUPER PISA,I-56100 PISA,ITALY
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 418卷 / 01期
关键词：
D O I：
10.1016/0022-328X(91)86352-Q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Pd(PtBu3)2 with the strong acids H3O+ X-, (X = BF3OH, BF4), gives the thermally unstable hydrides trans-[(tBu3P)2Pd(H)(H2O)]X. The thermally stable hydrides trans-[(tBu3P)2Pd(H) (CH3CN)]X were obtained by substitution of the water molecule by CH3CN. The reaction of the aquo-hydrides with CO, yielding [Pd(CO)(PtBu3)]2 and the crystal structure of trans[[(tBu3P)2Pd(H) (CH3CN)]BPh4 are also reported.
引用
收藏
页码：119 / 126
页数：8
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