SYNTHESIS AND CHARACTERIZATION OF MIXED-LIGAND COMPLEXES OF YTTRIUM AND LANTHANIDE(III)-BIS(PHENYLSULPHINYL)PROPANE AND BIPYRIDYL

被引：8

作者：

ZHANG, RH ^{[1
]}

WU, XY ^{[1
]}

ZHAO, FZ ^{[1
]}

ZHAN, YL ^{[1
]}

机构：

[1] CHANGCHUN INST APPL CHEM,RARE EARTH CHEM & PHYS LAB,CHANGCHUN,PEOPLES R CHINA

来源：

POLYHEDRON | 1995年 / 14卷 / 05期

关键词：

D O I：

10.1016/0277-5387(94)00277-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of novel mixed ligand complexes of yttrium and lanthanide(III) ions with bis(phenylsulphinyl)propane and bipyridyl have been synthesized. The complexes were assigned the formula [Ln(bphsp)(3)(bipy) (ClO4)](ClO4)(2) (bphsp = bis(phenylsulphinyl)propane; bipy = bipyridyl; Ln = La, Pr, Eu, Gd, Tb, Ho, Er, Yb, Y) and [Nd(bphsp)(3)(bipy)(ClO4)](ClO4)(2) . 2H(2)O on the basis of analytical, conductance and spectral (IR, electronic) and magnetic data. In all cases, the lanthanide ion bonds to the sulphoxide moiety via the oxygen atoms and to the bipy via the nitrogen atom. The coordination number of the complexes may be nine. The spectral strength for emission spectrum (D-5(0) --> F-7(2)) of Eu(bphsp)(3)(bipy)(ClO4)(3) was increased by the coordination of bipy.

引用

页码：629 / 633

页数：5

共 50 条

[1] SYNTHESIS AND CHARACTERIZATION OF NEW LANTHANIDE COMPLEXES OF BIS(PHENYLSULPHINYL)PROPANE
ZHANG, RH
ZHAN, YL
CHEN, JT
[J]. POLYHEDRON, 1994, 13 (12) : 1881 - 1885
[2] MIXED-LIGAND COMPLEXES OF LANTHANIDE PERCHLORATE WITH 1,3-BIS(PHENYLSULPHINYL)PROPANE AND 1,10-PHENANTHROLINE
ZHANG, RH
WANG, HM
ZHU, C
ZHANG, YL
CHEN, JT
[J]. POLYHEDRON, 1995, 14 (20-21) : 3037 - 3040
[3] Synthesis, Characterization, and Photocatalytic Activity of Mixed-Ligand Cerium(III) and Bismuth(III) Complexes
Latif, Shoomaila
Saeed, Maimoona
Imran, Muhammad
Javaid, Ayesha
Hira, Uzma
Mitu, Liviu
[J]. JOURNAL OF CHEMISTRY, 2022, 2022
[4] Synthesis and characterization of new mixed-ligand lanthanide-phthalocyanine cation radical complexes
Nemykin, VN
Chernii, VY
Volkov, SV
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (18): : 2995 - 2999
[5] SYNTHESIS AND CHARACTERIZATION OF MIXED-LIGAND COMPLEXES OF PLATINUM
CADIZ, IIM
MUIR, MM
PENABAD, J
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 187 (APR): : 151 - INOR
[6] Mn(III) mixed-ligand complexes with bis-pyrazolones and ciprofloxacin drug: synthesis, characterization and antibacterial activities
Modi, C. K.
Jani, D. H.
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2011, 25 (06) : 429 - 436
[7] SYNTHESIS AND STUDY OF CO(III) MIXED-LIGAND COMPLEXES
TSKITISHVILI, MG
SHVELASHVILI, AE
MIKADZE, II
CHERELASHVILI, MV
[J]. KOORDINATSIONNAYA KHIMIYA, 1991, 17 (01): : 68 - 75
[8] Synthesis and characterization of mixed-ligand ruthenium(III) complexes with oxalate and acetylacetonate ions
Hoshino, Y
Eto, M
Fujino, T
Yukawa, Y
Ohta, T
Endo, A
Shimizu, K
Satô, GP
[J]. INORGANICA CHIMICA ACTA, 2004, 357 (02) : 600 - 604
[9] Aqueous Medium Synthesis and Characterization of Mixed-Ligand Molecular Complexes of Manganese(III)
Bhowmik, Kanti Ranjan Nath
[J]. ORIENTAL JOURNAL OF CHEMISTRY, 2024, 40 (01) : 202 - 208
[10] Facile synthesis of mixed-ligand bis(dicarbollyl) complexes of nickel
Safronov, Alexander V.
Tran, Doanh X.
Sevryugina, Yulia V.
Jalisatgi, Satish S.
Hawthorne, M. Frederick
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 805 : 15 - 18

← 1 2 3 4 5 →