POLYMERIZATION OF CU-2+ CONTAINING ACRYLAMIDE IN CONCENTRATED AQUEOUS-SOLUTION, INITIATED BY POTASSIUM PERSULFATE, IN THE PRESENCE OF AMMONIA

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作者
OSMANOV, TO
MARKOV, VE
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O69 [应用化学];
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081704 ;
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The polymerization of acrylamide was studied in the presence of [CuSo4] = (0.23-9.6) . 10(-4) M and NH4OH at a mole ratio [NH4OH]:[CuSo4] from 0 to 8 or more. It was established that at [NH4OH]:[CuSO4] = 2 a certain decrease in the reaction rate and increase in the molecular weight are observed, whereas at 4 and above the opposite process occurs - a sharp increase in the reaction rate and decrease in the molecular weight of the polymer.
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页码:328 / 332
页数:5
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