STRUCTURE OF 1,1'-2,2'-BIS(OXYBISMETHYLENE)FERROCENE

被引：0
|
作者：
GEIB, SJ
RAO, SJ
PETTER, RC
机构：
[1] Department of Chemistry, Unversity of Pittsburgh
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷
关键词：
D O I：
10.1107/S0108270191004250
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
C14H14FeO2, M(r) = 270.1, monoclinic, P2(1)/n, a = 12.884 (6), b = 12.012 (6), c = 14.442 (7) angstrom, beta = 101.45 (3)-degrees, V = 2191 (2) angstrom 3, Z = 8, D(x) = 1.638 g cm-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 13.58 cm-1, F(000) = 1120. T = 296 K, R(F) = 4.75% for 2654 reflections with F(o) > 5-sigma(F(o)) and 308 parameters. The complex is a doubly bridged ferrocene which is the product of the acid-catalyzed double dehydration of 1,1',2,2'-tetrakis(hydroxymethyl)ferrocene. The molecule crystallizes with the two oxybismethylene bridges in an endo-exo conformation. Comparisons made with related bridged ferrocenes suggest that the preference for endo-exo geometry derives from favorable dipole-dipole interaction between the ether oxygens.
引用
收藏
页码：25 / 27
页数：3
相关论文
共 50 条
  • [41] Crystal structure of 1,1′-bis(xhlorodimethylsilyl)ferrocene, C14H20Cl2FeSi2
    Kempe, R
    Spannenberg, A
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1997, 212 (03): : 479 - 480
  • [42] Coordination chemistry of 1,1'-bis(2-pyridyl)ferrocene in palladium(II) and platinum(II) complexes and reaction of (BPF)Pd(Me)Cl with CO. X-ray structure of (1,1'-bis(2-pyridyl)ferrocene)Pd(Me)Cl and (1,1'-bis(2-pyridyl)ferrocene)[PtCl2(CH2=CH2)](2)
    Delis, JGP
    vanLeeuwen, PWNM
    Vrieze, K
    Veldman, N
    Spek, AL
    Fraanje, J
    Goubitz, K
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 514 (1-2) : 125 - 136
  • [43] 2,2′-Bipyrimidine-1,1′-diium bis(triiodide)-2,2′-bipyrimidine-water (1/2/2)
    Ha, Kwang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2558 - U1687
  • [44] CRYSTAL-STRUCTURE OF 1,1-BIS(BENZOYLAMINO)-2,2-DIMETHYLPROPANE
    HONDA, K
    GOTO, M
    KOJIMA, I
    SHIBUYA, I
    ANALYTICAL SCIENCES, 1994, 10 (01) : 137 - 138
  • [45] THERMAL DECOMPOSITION OF 1,1'-AZOBUTANE, 1,1'-AZOISOBUTANE, 2,2'-AZOBUTANE AND 2,2'-AZOISOBUTANE
    BLACKHAM, AU
    EATOUGH, NL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (15) : 2922 - &
  • [46] 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL - A NEW AXIALLY DISSYMMETRIC BIS (TRIARYL)PHOSPHINE
    MIYASHITA, A
    TAKAYA, H
    NOYORI, R
    ACS SYMPOSIUM SERIES, 1982, 185 : 274 - 277
  • [47] [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]TETRACARBONYLMOLYBDENUM
    RHEINGOLD, AL
    HAGGERTY, BS
    EDWARDS, AJ
    HOUSECROFT, CE
    HATTERSLEY, AD
    HINZE, N
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 1411 - 1414
  • [48] Resolution of 1,1 '-Bi-2-Naphthol; (R)-(+)- and (S)-(-)- 2,2 '-Bis(diphenylphosphino)-1,1 '-binaphthyl (BINAP)
    Hughes, David L.
    ORGANIC SYNTHESES, 2014, 91 : 1 - 11
  • [49] TRIPHENYLSTANNYLFERROCENE AND 1,1'-BIS(TRIPHENYLSTANNYL)FERROCENE
    YAMIN, BM
    FUN, HK
    YIP, BC
    SHAWKATALY, OB
    TEOH, SG
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 1551 - 1555
  • [50] (S)-2,2′-bis(4-nitro-2-pyridyloxy)-1,1′-binaphthalene
    Wang, RH
    Xu, LJ
    Chen, G
    Zhou, ZY
    Hong, MC
    Cao, R
    Chan, ASC
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O865 - O867
12345