STRUCTURE OF 1,1'-2,2'-BIS(OXYBISMETHYLENE)FERROCENE

被引：0

作者：

GEIB, SJ

RAO, SJ

PETTER, RC

机构：

[1] Department of Chemistry, Unversity of Pittsburgh

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270191004250

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C14H14FeO2, M(r) = 270.1, monoclinic, P2(1)/n, a = 12.884 (6), b = 12.012 (6), c = 14.442 (7) angstrom, beta = 101.45 (3)-degrees, V = 2191 (2) angstrom 3, Z = 8, D(x) = 1.638 g cm-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 13.58 cm-1, F(000) = 1120. T = 296 K, R(F) = 4.75% for 2654 reflections with F(o) > 5-sigma(F(o)) and 308 parameters. The complex is a doubly bridged ferrocene which is the product of the acid-catalyzed double dehydration of 1,1',2,2'-tetrakis(hydroxymethyl)ferrocene. The molecule crystallizes with the two oxybismethylene bridges in an endo-exo conformation. Comparisons made with related bridged ferrocenes suggest that the preference for endo-exo geometry derives from favorable dipole-dipole interaction between the ether oxygens.

引用

页码：25 / 27

页数：3

共 50 条

[21] Electrochemistry of 1,1′-Bis(2,4-dialkylphosphetanyl)ferrocene and 1,1′-Bis(2,5-dialkylphospholanyl)ferrocene Ligands: Free Phosphines, Metal Complexes, and Chalcogenides
Mandell, Chelsea L.
Kleinbach, Shannon S.
Dougherty, William G.
Kassel, W. Scott
Nataro, Chip
INORGANIC CHEMISTRY, 2010, 49 (20) : 9718 - 9727
[22] STRUCTURE AND METAL COORDINATION OF THE DIPHOSPHINE 2,2'-BIS((DIPHENYLPHOSPHINL)METHYL)-1,1'-BINAPHTHYL (NAPHOS)
HERRMANN, WA
SCHMID, R
KOHLPAINTNER, CW
PRIERMEIER, T
ORGANOMETALLICS, 1995, 14 (04) : 1961 - 1968
[23] STRUCTURE AND METAL COORDINATION OF THE DIPHOSPHANE 2,2'-BIS((DIPHENYLPHOSPHINO)METHYL)-1,1'-BIPHENYL (BISBI)
HERRMANN, WA
KOHLPAINTNER, CW
HERDTWECK, E
KIPROF, P
INORGANIC CHEMISTRY, 1991, 30 (22) : 4271 - 4275
[24] [1,1′-bis(diphenylphosphino)ferrocene]dichloropalladium/1,1′-bis(diphenylphosphino)ferrocene catalyzed synthesis of 2,3-diamino-1,4-naphthoquinones
Wang, Xiao Lei
Zheng, Xiu Fang
Wang, Lei
Reiner, John
Xie, Wei Lin
Chang, Jun Biao
SYNTHESIS-STUTTGART, 2007, (07): : 989 - 998
[25] THE STRUCTURE AND CONFORMATION OF [1,1'-BIPYRROLIDINE]-2,2'-DITHIONE
MICHAEL, JP
BILLING, DG
BOEYENS, JCA
CARLTON, L
DENNER, L
HINDMARCH, IA
JOURNAL OF MOLECULAR STRUCTURE, 1990, 238 : 391 - 401
[26] SYNTHESIS AND CRYSTAL-STRUCTURE OF 1,1',2,2'-BIS(1,2,3-TRITHIA-[3])FERROCENOPHANE
LONG, NJ
SHARKEY, SJ
HURSTHOUSE, MB
MAZID, MA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (01): : 23 - 26
[27] rac-2,2′-Bis(diphenylphosphinoyl)-1,1′-binaphthyl
Thibault, Marie-Helene
Fontaine, Frederic-Georges
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O2087 - O2088
[28] Synthesis and characterization of 1,1′-bis(2-ethanol)ferrocene.
Barry, KP
Nataro, C
Herber, RH
Rheingold, AL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U735 - U735
[29] POLYMERIC (2,2'-TRIMETHYLENEDIPYRIDINE 1,1'-DIOXIDE)BIS[DICHLOROMERCURY(II)]
ALSHAIKHKADIR, K
DREW, MGB
HOLT, P
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (MAR): : 939 - 941
[30] (R)-(+)- and (S)-(-)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl (BINAP)
Cai, DW
Payack, JF
Bender, DR
Hughes, DL
Verhoeven, TR
Reider, PJ
ORGANIC SYNTHESES, VOL 76 - 1999, 1999, 76 : 6 - 11

← 1 2 3 4 5 →