Unexpected Transformations of Aziridino-phosphazenes Built on ortho-Phenylene Scaffolds

被引：0

作者：

Marin-Luna, Marta ^{[1
]}

Diaz-Moreno, Javier ^{[1
]}

Vidal, Angel ^{[1
]}

Alajarin, Mateo ^{[1
]}

机构：

[1] Univ Murcia, Fac Quim, Dept Quim Organ, Reg Campus Int Excellence Campus Mare Nostrum, Murcia 30100, Spain

来源：

18TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY | 2014年

关键词：

aziridine; heterocumulenes; 3+2] cycloaddition; aza-Wittig reaction;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Staudinger imination reaction of alkyl 3-(o-azidophenyl)aziridino-2-carboxylates with trimethyl phosphine promotes an intramolecular aza-Wittig reaction between the non-isolated putative phosphazenes and the carbonyl group of the ester function. A further hydrolytic treatment of the resulting iminoesters led ultimately to 3-amino-2-quinolones via a molecular reorganization at the aziridino fragment.

引用

页数：8

共 1 条

[1] Extended enantiopure ortho-phenylene ethylene (o-OPE)-based helical systems as scaffolds for supramolecular architectures: a study of chiroptical response and its connection to the CISS effect
Ortuno, Ana M.
Reine, Pablo
Resa, Sandra
Alvarez de Cienfuegos, Luis
Blanco, Victor
Paredes, Jose Manuel
Mota, Antonio J.
Mazzeo, Giuseppe
Abbate, Sergio
Ugalde, Jesus M.
Mujica, Vladimiro
Longhi, Giovanna
Miguel, Delia
Cuerva, Juan Manuel
ORGANIC CHEMISTRY FRONTIERS, 2021, 8 (18) : 5071 - 5086

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