PARTIALLY FLUORINATED ENAMINES AND THEIR ELECTROCHEMICAL FLUORINATION

被引：21

作者：

MOLDAVSKY, DD

KAUROVA, GI

BISPEN, TA

FURIN, GG

机构：

[1] NOVOSIBIRSK ORGAN CHEM INST,NOVOSIBIRSK 630090,RUSSIA

[2] ST PETERSBURG APPL CHEM INST,ST PETERSBURG 197198,RUSSIA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 63卷 / 03期

关键词：

D O I：

10.1016/S0022-1139(00)80563-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of hexafluoropropylene, its dimers and trimers, and perfluoro-1-ethylcyclo-hex-1-ene with secondary amines (dipropylamine, dibutylamine and diallylamine) have been shown to form enamines. The enamines were electrochemically fluorinated in anhydrous hydrogen fluoride. This paper reports the electrochemical fluorination data for the fluorination of tripropylamine, tributylamine, triamylamine and the partially fluorinated enamines. The structures of the products have been confirmed by F-19 NMR and GC-MS methods.

引用

页码：193 / 201

页数：9

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