HYDRODEMETALATION OF VANADYLPORPHIRINES ON MO AND NI-MO SULFIDE CATALYSTS SUPPORTED ON SIBUNIT

被引：0
|
作者：
KOROLKOV, VV [1 ]
DORONIN, VP [1 ]
STARTSEV, AN [1 ]
KLIMOV, OV [1 ]
TUREKHANOVA, RN [1 ]
DUPLYAKIN, VK [1 ]
机构：
[1] BORESKOV INST CATALYSIS,NOVOSIBIRSK 630090,RUSSIA
来源：
KINETICS AND CATALYSIS | 1994年 / 35卷 / 01期
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D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The hydrodemetallation (HDM) reaction of VO-tetra(tert-butylphenyl)porphine on Ni-Mo and Mo catalysts, supported on a carbon carrier of the Sibunit type, proceeds in the same manner as that on the catalysts supported on mineral carriers. Ni-Mo/Sibunit and Mo/Sibunit catalysts exhibit high activity in the conversion of model compounds. A fast activity drop at the initial period, which is typical of the catalysts supported on alumina, is not inherent to these catalysts.
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页码：84 / 86
页数：3
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