LASER-PULSE PHOTOLYSIS OF 4,4'-BIPYRIDINE - A TIME-RESOLVED RAMAN INVESTIGATION

被引:14
|
作者
POIZAT, O [1 ]
VENTURA, M [1 ]
BUNTINX, G [1 ]
机构
[1] UNIV SCI TECH LILLE FLANDRES ARTOIS,CNRS,SPECTROCHIM INFRAROUGE & RAMAN LAB,F-59655 VILLENEUVE DASCQ,FRANCE
关键词
4; 4'; bipyridine Raman spectroscopy photoreduction radical radical cation photolysis;
D O I
10.1080/00387019008054451
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The 266nm photolysis products of 4,4'-bipyridine in cyclohexane, acetonitrile, methanol, hexafluoro-propanol and H2O/HCl solutions have been investigated by time-resolved Raman spectroscopy in the nanosecond time scale. The identification of some photochemical transients and the characterization of their structure and electronic configuration are discussed. © 1990, Taylor & Francis Group, LLC. All rights reserved.
引用
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页码:701 / 712
页数:12
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