THE CRYSTAL-STRUCTURES OF 2 MERCURY PERRHENATES

被引：24
|
作者：
SCHRIEWERPOTTGEN, MS [1 ]
JEITSCHKO, W [1 ]
机构：
[1] UNIV MUNSTER,INST ANORGAN CHEM,D-48149 MUNSTER,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 11期
关键词：
CRYSTAL STRUCTURE; HG-2(REO4)(2); (HG-2-CENTER-DOT-2HGO)(REO4)(2);
D O I：
10.1002/zaac.19946201104
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The mercury perrhenates with the empirical formulas HgReO4 and Hg2ReO5 were prepared by annealing powdered mixtures of mercury(II)oxide and mercury(II)metaperrhenate Hg(ReO4)(2), in sealed silica tubes. Their crystal structures were determined from single-crystal X-ray data. HgReO4 crystallizes dimeric with nearly linear O3Re-O-Hg-Hg-O-ReO3 molecular units and Hg2ReO5 has a solid state structure, where Hg(I) and Hg(II) together with oxygen atoms form 14-membered rings, which are condensed to two-dimensionally infinite polycationic nets of composition (Hg2+.2HgO)(n). These nets are separated from each other by tetrahedral ReO4- anions.
引用
收藏
页码：1855 / 1860
页数：6
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