FUNCTIONALIZATION OF THE ALIPHATIC CHAIN IN 4-NITRO-N,N-DIETHYLANILINE - DIRECT TRIFLUOROACETYLATION OF THE BETA-CARBON-ATOM

被引：0

作者：

MOSKALEV, NV ^{[1
]}

OGORODNIKOV, VD ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST OIL CHEM,TOMSK 634050,RUSSIA

来源：

MENDELEEV COMMUNICATIONS | 1995年 / 05期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of 4-nitro-N,N-diethylaniline 1 with trifiuoroacetic anhydride 2 at 120 degrees C unexpectedly gives trans-1,1,1-trifluoro-4-[N-ethyl-N-(4-nitrophenylamino)]but-3-en-2-one 3 in good yield.

引用

页码：197 / 198

页数：2

共 5 条

[1] Direct Reductive N-Functionalization of Aliphatic Nitro Compounds
Rauser, Marian
Ascheberg, Christoph
Niggemann, Meike
CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (16) : 3970 - 3974
[2] Thermodynamics of amine plus ketone mixtures: Volumetric, speed of sound data and viscosity at 303.15 K and 308.15 K for the binary mixtures of N,N-diethylaniline plus aliphatic ketones (C3-C5)+4-methyl-2-pentanone
Gowrisankar, Manukonda
Venkateswarlu, Ponneri
Sivakumar, Kasibhatta
Sivarambabu, Sakamuri
ARABIAN JOURNAL OF CHEMISTRY, 2017, 10 : S2625 - S2636
[3] SYNTHETIC REACTIONS OF ALIPHATIC NITRO-COMPOUNDS .14. SYNTHESIS OF "4-(BETA-D-RIBOFURANOSYL)ISOXAZOLINE N-OXIDE DERIVATIVES
KAJI, E
ZEN, S
SYNTHETIC COMMUNICATIONS, 1979, 9 (03) : 165 - 170
[4] One-dimensional metal atom chain [Ru(CO)4]n as a catalyst precursor-Hydroformylation of 1-hexene using carbon dioxide as a reactant
Kontkanen, Maija-Liisa
Oresmaa, Larisa
Moreno, M. Andreina
Janis, Janne
Laurila, Elina
Haukka, Matti
APPLIED CATALYSIS A-GENERAL, 2009, 365 (01) : 130 - 134
[5] On the Mechanism of Intramolecular Nitrogen-Atom Hopping in the Carbon Chain of C6N Radical: A Plausible 3c-4e Crossover (π)over-cap Long-Bond
Kaur, Gurpreet
Vikas
JOURNAL OF COMPUTATIONAL CHEMISTRY, 2014, 35 (21) : 1568 - 1576

← 1 →