IN-SITU CHARACTERIZATION OF CONDUCTING POLYMERS BY MEASURING DYNAMIC CONTACT ANGLES WITH WILHELMYS PLATE TECHNIQUE

被引:22
|
作者
TEASDALE, PR [1 ]
WALLACE, GG [1 ]
机构
[1] UNIV WOLLONGONG,DEPT CHEM,INTELLIGENT POLYMER RES LAB,WOLLONGONG,NSW 2522,AUSTRALIA
来源
REACTIVE POLYMERS | 1995年 / 24卷 / 03期
基金
澳大利亚研究理事会;
关键词
POLYPYRROLE; DERIVATIZED PYRROLE; SUBSTRATE EFFECT; DYNAMIC CONTACT ANGLE; WILHELMYS PLATE TECHNIQUE;
D O I
10.1016/0923-1137(95)94036-X
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Dynamic contact angle analysis with Wilhelmy's plate technique was found to be useful for characterizing the chemical interactions that occur on conducting polymers. The derivatized pyrroles, 3-carboxy-4-methylpyrrole and 3-carbethoxy-4-methylpyrrole, along with pyrrole, were used to prepare polymers with a range of polarities. The predicted trend of polarity, based upon the chemical structures of the polymers, was verified with the technique. It has also been shown that the substrate employed during electropolymerization process plays a major role in determining the properties of the resultant polymer.
引用
收藏
页码:157 / 164
页数:8
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