IONIC INTERACTIONS IN MCF3SO3-POLYETHER COMPLEXES CONTAINING MONOVALENT, DIVALENT AND TRIVALENT CATIONS

被引：72
|
作者：
PETERSEN, G
TORELL, LM
PANERO, S
SCROSATI, B
DASILVA, CJ
SMITH, M
机构：
[1] UNIV ROMA LA SAPIENZA,DIPARTIMENTO CHIM,I-00185 ROME,ITALY
[2] UNIV MINHO,DEPT CHEM,P-4719 BRAGA,PORTUGAL
来源：
SOLID STATE IONICS | 1993年 / 60卷 / 1-3期
关键词：
D O I：
10.1016/0167-2738(93)90274-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ion association has been investigated by Raman scattering from triflate salts M (CF3SO3)x in PEO (400) for various cationic substitutions (M=Li+, Ca2+, Cu2+, and Nd3+) and for OH-capped, respectively CH3-Capped, polymer chains. The ion-ion interaction shows different temperature behavior in different systems. The observations are discussed in terms of recent theories which consider volume changes (electrostriction) in the salt dissociation process.
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页码：55 / 60
页数：6
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