LEWIS BASE-INDUCED REARRANGEMENT OF PRIMARY ETHYN-1-YLPHOSPHINES, A NEW AND EFFICIENT ROUTE TO PHOSPHAALKYNES

被引：37

作者：

GUILLEMIN, JC

JANATI, T

DENIS, JM

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 05期

关键词：

D O I：

10.1039/c39920000415

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phosphaalkynes bearing primary carbon substituents are prepared in good yield by low-temperature Lewis base-induced rearrangement of primary ethyn-1-ylphosphines; the mechanism involves a P-unsubstituted phosphaallene intermediate.

引用

页码：415 / 416

页数：2

共 45 条

[1] EFFICIENT SYNTHESIS OF UNSTABILIZED PHOSPHAALKENES BY STEREOSELECTIVE LEWIS BASE-INDUCED REARRANGEMENT OF VINYLPHOSPHINES
GAUMONT, AC
GUILLEMIN, JC
DENIS, JM
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[2] A New Cyclobutane Ring Contraction: the Base-Induced Rearrangement of an a-Bromocyclobutanecarboxylic Ester
Tetrahedron Lett, 5 (623):
[3] New Development of Base-Induced Sommelet-Hauser Rearrangement of Ammonium Ylides
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[4] An unexpected base-induced [1,4]-phospho-Fries rearrangement
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[5] A new cyclobutane ring contraction: The base-induced rearrangement of an alpha-bromocyclobutanecarboxylic ester
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[6] A convenient synthesis of new isolable phosphaalkenes using the base-induced rearrangement of secondary vinylphosphines
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Gates, DP
INORGANIC CHEMISTRY, 2004, 43 (12) : 3719 - 3723
[7] BASE-INDUCED REARRANGEMENT OF 1-TRIMETHYLSILYLPROPARGYL ALCOHOL - GENERATION OF LITHIATED TRIMETHYLSILOXYALLENES AND THEIR REACTIONS
KUWAJIMA, I
KATO, M
TETRAHEDRON LETTERS, 1980, 21 (07) : 623 - 626
[8] HALOHYDRINS OF ISOQUINOLINE REISSERT COMPOUNDS - BASE-INDUCED REARRANGEMENT REACTIONS PROVIDING ISOCHROMENES AND NEW ISOQUINOLINES
KIRBY, GW
MACKINNON, JWM
ELLIOTT, S
UFF, BC
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (05): : 1298 - 1302
[9] BASE-INDUCED HYDROLYTIC REARRANGEMENT OF TRANS-GAMMA-BROMODYPNONE TO 1,2-DIBENZOYLETHANE
LUTZ, RE
SLADE, LT
ZORETIC, PA
JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (05): : 1358 - &
[10] Formation of a pentacoordinate 1,2-oxastannetanide by novel base-induced rearrangement of a bis(β-hydroxyalkyl)stannane
Naganuma, K
Kawashima, T
Okazaki, R
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1997, 124 : 513 - 516

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