THE SYNTHESIS OF OCTAHEDRAL MIXED BIS-ALKYNE AND ALKYNE ALKENE COMPLEXES OF TUNGSTEN

被引：12
|
作者：
CLARK, GR
NIELSON, AJ
RAE, AD
RICKARD, CEF
机构：
[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND
[2] UNIV NEW S WALES,DEPT CHEM,SYDNEY,NSW,AUSTRALIA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 15期
关键词：
D O I：
10.1039/c39920001069
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Replacement of a phosphine ligand in [WCl2(PhC2Ph)(PMe3)3] by PhC = CPh, PhC = CH and HC = CH, or reduction of [WCl3(PhC2Ph)(PMe3)2] in the presence of MeC2Me and Me(CH2)2C2Me yields mixed bis-alkyne complexes; under ethylene or propene the reduction reactions afford mixed alkyne-alkene complexes, and the structure of [WCl2(PhC2Ph)(CH2 = CH2)(PMe3)2] has been confirmed by X-ray crystallography.
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收藏
页码：1069 / 1070
页数：2
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