MECHANISM OF THE ACCELERATION OF ELECTRON-TRANSFER PROCESSES OCCURRING NEAR AN INTERFACE BETWEEN IMMISCIBLE LIQUIDS

被引:0
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作者
KHARKATS, YI
机构
来源
SOVIET ELECTROCHEMISTRY | 1990年 / 26卷 / 09期
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中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Electron-transfer rates near an interface between immiscible liquids were investigated as functions of the positions of the electron donor and acceptor relative to this interface, in terms of a simple model for the influence of reorganization of the polar medium on the activation energy of charge-transfer processes. It was shown that under certain conditions, the electron-transfer rates should rise to values several times higher than those found in the interior of each of the phases.
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页码:1032 / 1039
页数:8
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