MU-OXO, MU-SULFIDO COMPLEXES OF OXOMOLYBDENUM(V) WITH CARBOXYLATE LIGANDS

被引：4
|
作者：
DOADRIOVILLAREJO, AL
CALABUIG, MT
RAGEL, CV
DOADRIOLOPEZ, A
机构：
[1] Departamento de Química Inorgánica y Bioinorgánica, Facultad de Farmacia, Universidad Complutense, Madrid
来源：
TRANSITION METAL CHEMISTRY | 1991年 / 16卷 / 05期
关键词：
D O I：
10.1007/BF01024319
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We report the synthesis and study of new Mo(V) dimeric complexes with oxosulphido bridges and n-pentyl, n-hexyl, n-heptyl, iso-octyl, cyclohexyl and phenyl carboxylates as coligands. The complexes, of general formula Mo2O3S(RCO2)2, are compared to the Mo(v) carboxylates with monoxo and dioxo bridges. Their i.r. and electronic spectra are sensitive to substitution of sulphur atoms in the bridge system. The results are discussed in the light of the structural information available for oxomolybdenum(V) complexes.
引用
收藏
页码：508 / 510
页数：3
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