SYNTHESIS, CHARACTERIZATION, AND STRUCTURAL STUDY OF RE(2,4-C7H11)(H)2(P(C6H5)3)2

被引:5
|
作者
WALDMAN, TE
RHEINGOLD, AL
ERNST, RD
机构
[1] UNIV DELAWARE, DEPT CHEM, NEWARK, DE 19716 USA
[2] UNIV UTAH, DEPT CHEM, SALT LAKE CITY, UT 84112 USA
关键词
D O I
10.1016/0022-328X(91)86229-J
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Re(2,4-C7H11)(H)2(P(C6H5)3)2 has been prepared from the reaction of ReH7(P(C6H5)3)2 with 2,4-dimethyl-1,3-pentadiene. A single crystal X-ray diffraction study has revealed a structure with nonequivalent phosphines but equivalent hydride ligands, just the opposite situation as observed for a cyclohexadienyl analog.
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页码:331 / 337
页数:7
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