BIS(ETA-5-TRICYCLO[5.2.1.0/2,6]DECA-2,5,8-TRIEN-4-YL) DERIVATIVES OF THE GROUP-IV TRANSITION-METALS

被引：6

作者：

BHIDE, VV ^{[1
]}

RINALDI, PL ^{[1
]}

FARONA, MF ^{[1
]}

机构：

[1] UNIV AKRON,DEPT CHEM,AKRON,OH 44325

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 01期

关键词：

Metallocene Dichlorides - Transition Metal Compounds;

D O I：

10.1021/om00115a019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metallocene dichloride derivatives of titanium, zirconium, and hafnium were prepared from tricyclo-[5.2.1.02,6]deca-2,5,8-triene and the corresponding metal tetrachlorides. These compounds were characterized as existing primarily in the endo,endo and exo,endo forms by two-dimensional1H NMR studies. These results were unexpected, in that theory predicts primarily exo,exo isomers should be preferred. A study on bis(isodicyclopentadienyl)titanium dichloride revealed the compound to exist in two major isomeric forms: exo,endo and exo,exo. © 1990, American Chemical Society. All rights reserved.

引用

页码：123 / 126

页数：4

共 45 条

[1] REDOX BEHAVIOR OF FERROCENE DERIVATIVES .2. BIS(ETA-5-TRICYCLO[5.2.1.02,6]DECA-2,5,8-TRIEN-6-YL)IRON AND RELATED MOLECULES
GALLUCCI, JC
OPROMOLLA, G
PAQUETTE, LA
PARDI, L
SCHIRCH, PFT
SIVIK, MR
ZANELLO, P
INORGANIC CHEMISTRY, 1993, 32 (11) : 2292 - 2297
[2] Synthesis,Structure,and Ring-opening Metathesis Polymerization of η~5-Pentamethylcyclopentadienyl-(η~5-exo-tricyclo [5.2.1.02,6]deca-2,5,8-trien-6-yl) Iron
ZHAO Xi
ChemicalResearchinChineseUniversities, 2009, 25 (05) : 662 - 665
[3] Synthesis, Structure, and Ring-opening Metathesis Polymerization of η5-Pentamethylcyclopentadienyl-(η5-exo-tricyclo[5.2.1.02,6]deca-2,5,8-trien-6-yl) Iron
Zhao Xi
Li Bin
Xu Shan-sheng
Song Hai-bin
Wang Bai-quan
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2009, 25 (05) : 662 - 665
[4] BIS(2,3,4,6,7-ETA-5-BICYCLO[3.2.2]NONA-2,6,8-TRIEN-4-YL)IRON, A FERROCENE ANALOG WITH SEPARATED ALLYL AND OLEFIN SYSTEMS
BLUMEL, J
KOHLER, FH
MULLER, G
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (14) : 4846 - 4848
[5] SYNTHESIS AND STRUCTURE OF A CARBONYL-BRIDGED DIMERIC COMPOUND CONTAINING GROUP-IV AND GROUP-VIII TRANSITION-METALS - (ETA-5-C5H5)CO(MU-CO)(MU-ETA-1,ETA2-CO)ZR(ETA5-C5ME5)2
BARGER, PT
BERCAW, JE
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 201 (02) : C39 - C44
[6] CHARACTERIZATION OF A MINOR PRODUCT OF REACTION OF DIIRON NONACARBONYL WITH "CIS-BICYCLO[6.2.0]DECA-2,4,6-TRIENE - TRANS-DI-MU-BIS(2,3,4,5,6-PENTAHAPTO-TRICYCLO[6.2.0.0-2-6]DECA-2,4-DIEN-6-YL)DICARBONYLDIIRON(FE-FE)
COTTON, FA
FRENZ, BA
TROUP, JM
DEGANELL.G
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 59 (OCT1) : 317 - 327
[7] SYNTHESIS AND STRUCTURE OF DIMERIC METALLOCENE DERIVATIVES OF TRANSITION-METALS OF GROUP-IV AND GROUP-V - CRYSTAL AND MOLECULAR-STRUCTURES OF (ETA-5-ETA-5-C10H8)(C5H5)2NB2(MU-H)(MU-OET) AND (ETA-5-ETA-5-C10H8)(C5H5)2TI2(MU-H)(MU-CL)
PEREVALOVA, EG
URAZOWSKI, IF
LEMENOVSKII, DA
SLOVOKHOTOV, YL
STRUCHKOV, YT
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 289 (2-3) : 319 - 329
[8] ORGANOMETALLOIDAL DERIVATIVES OF THE TRANSITION-METALS .26. SYNTHESIS AND PHOTOCHEMICAL REACTIVITY OF TRANSITION-METAL-DISUBSTITUTED DISILANES (ETA-5-C5H5)FE(CO)2SIME2SIME2FE(CO)2(ETA-5-C5H5) AND (ETA-5-C5H5)FE(ETA-5-C5H4)SIME2SIME2(ETA-5-C5H4)FE(ETA-5-C5H5)
PANNELL, KH
SHARMA, H
ORGANOMETALLICS, 1991, 10 (04) : 954 - 959
[9] PYRROLYL COMPLEXES OF THE EARLY TRANSITION-METALS .1. SYNTHESIS AND CRYSTAL-STRUCTURE OF (ETA-5-C5H5)2TI(ETA-1-NC4H4)2, (ETA-5-C5H5)2ZR(ETA-1-NC4H4)2, AND [NA(THF)6]2[ZR(ETA-1-NC4H4)6]
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HUNTER, WE
ROGERS, RD
ATWOOD, JL
INORGANIC CHEMISTRY, 1980, 19 (08) : 2368 - 2374
[10] MULTIPLE BONDS BETWEEN MAIN GROUP ELEMENTS AND TRANSITION-METALS .36. METALLORGANIC OXIDES OF THE VANADIUM SERIES - DERIVATIVES OF THE KEY COMPOUND (ETA5-C5H5)VOCL2
HERRMANN, WA
WEICHSELBAUMER, G
KNEUPER, HJ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 319 (02) : C21 - C24

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