FORMATION OF BENZIMIDAZOLIUM SALT IN THE COMPLEXATION OF 2-SUBSTITUTED BENZIMIDAZOLE DERIVATIVE

被引：0
|
作者：
Sabithakala, T. [1 ]
Reddy, Venkata Ramana Ch [1 ]
机构：
[1] Jawaharlal Nehru Technol Univ Hyderabad CEH, Dept Chem, Hyderabad 500085, Andhra Pradesh, India
来源：
Heterocyclic Letters | 2016年 / 6卷 / 01期
关键词：
Benzimidazolium salt; crystal structure; tridentate ligand;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In an attempted synthesis of Zn(II) complex of a tridentate ligand[2-((1H-benzimidazol- 2-yl) methylamino) acetic acid] (BIG), benzimidazolium salt was formed instead of Zn(II) complex. Benzimidazolium salt was structurally characterized by single crystal Xray diffraction. The compound is crystallized in the monoclinic system and crystallographic details of X-Ray structure of benzimidazolium salt are : Space group: P2(1)/c, a (angstrom) = 7.021(6), b (angstrom) = 19.934(18), c (angstrom) = 9.869(9), V (angstrom(3)) = 1371(2), a ((degrees)) = 90, beta (degrees)= 96.858(14), gamma ((degrees))= 90, Z= 4, R factor was 0.1080 for 7381 observed reflections.
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页码：53 / 56
页数：4
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