REGIO-REVERSAL IN THERMAL AND PHOTOCHEMICAL REDUCTION OF 10-METHYLACRIDINIUM ION BY ALLYLIC SILANES AND STANNANES

被引：19

作者：

FUKUZUMI, S ^{[1
]}

FUJITA, M ^{[1
]}

OTERA, J ^{[1
]}

机构：

[1] OKAYAMA UNIV SCI,DEPT APPL CHEM,OKAYAMA 700,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 20期

关键词：

D O I：

10.1039/c39930001536

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermal reduction of 10-methylacridinium ion by allylic stannanes occurs via a polar mechanism to yield the dihydroacridines allylated at the gamma-position exclusively, while the photoallylation of 10-methylacridinium ion proceeds via the photoinduced electron transfer from allylic silanes and stannanes to the singlet excited state of 1 0-methylacridinium ion to yield mainly the alpha-adducts.

引用

页码：1536 / 1537

页数：2

共 9 条

[1] REDUCTION OF 10-METHYLACRIDINIUM ION BY ALKENES VIA PHOTOINDUCED ELECTRON-TRANSFER
FUJITA, M
FUKUZUMI, S
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (10): : 1915 - 1921
[2] Regioreversed thermal and photochemical education of 10-methylacridinium and 1-methylquinolinium ions by organosilanes and oraganostannanes
Fukuzumi, S
Fujita, M
Noura, S
Ohkubo, K
Suenobu, T
Araki, Y
Ito, O
JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (10): : 1857 - 1868
[3] PHOTOINDUCED HYDRIDE REDUCTION OF 10-METHYLACRIDINIUM ION BY ALKYLBENZENES IN THE PRESENCE OF PERCHLORIC-ACID
FUJITA, M
ISHIDA, A
MAJIMA, T
FUKUZUMI, S
TAKAMUKU, S
CHEMISTRY LETTERS, 1995, (02) : 111 - 112
[4] REDUCTION OF 10-METHYLACRIDINIUM ION WITH FATTY-ACIDS BY PHOTOINDUCED ELECTRON-TRANSFER REACTIONS
FUKUZUMI, S
KITANO, T
TANAKA, T
CHEMISTRY LETTERS, 1989, (07) : 1231 - 1234
[5] THE PHOTO-REDUCTION OF 10-METHYLACRIDINIUM ION BY TRIPHENYLPHOSPHINE THROUGH ONE-ELECTRON TRANSFER MECHANISM
YASUI, S
OHNO, A
TETRAHEDRON LETTERS, 1991, 32 (08) : 1047 - 1050
[6] THE CATALYTIC ROLE OF IODIDE-ION IODINE COUPLE IN THE PHOTO-REDUCTION OF 10-METHYLACRIDINIUM ION WITH DIPHENYLPHOSPHINE OXIDE
YASUI, S
SHIOJI, K
OHNO, A
YOSHIHARA, M
CHEMISTRY LETTERS, 1993, (08) : 1393 - 1396
[7] Cobalt(III) Porphyrin-catalysed Hydride Reduction of 10-Methylacridinium Ion and Hydrometallation of Alkenes and Alkynes by Tributyltin Hydride
Fukuzumi, Shunichi
Noura, Souta
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 1997, 1 (03) : 251 - 258
[8] PHOTOINDUCED ONE-ELECTRON REDUCTION OF 10-METHYLACRIDINIUM ION WITH GROUP-14 DIMETALLIC COMPOUNDS USING VISIBLE IRRADIATION
FUKUZUMI, S
KITANO, T
MOCHIDA, K
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (18) : 1236 - 1237
[9] SELECTIVE ONE-ELECTRON REDUCTION OF A CATIONIC SUBSTRATE, 10-METHYLACRIDINIUM ION, BY GROUP-4B DIMETALS, ME3SNSNME3, ME3SNGEME3, ME3SNSIME3, VIA RADICAL CHAIN REACTIONS
FUKUZUMI, S
KITANO, T
MOCHIDA, K
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (08) : 3246 - 3247

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