REACTION OF MOLECULAR-OXYGEN WITH C-60 - SPECTROSCOPIC STUDIES

被引：69

作者：

WERNER, H

SCHEDELNIEDRIG, T

WOHLERS, M

HEREIN, D

HERZOG, B

SCHLOGL, R

KEIL, M

BRADSHAW, AM

KIRSCHNER, J

机构：

[1] MAX PLANCK INST MIKROSTRUKTURPHYS,D-06120 HALLE,GERMANY

[2] MAX PLANCK GESELL,FRITZ HABER INST,D-14195 BERLIN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1994年 / 90卷 / 03期

关键词：

D O I：

10.1039/ft9949000403

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using both freshly sublimed powders and evaporated thin films, the reactivity of C-60 towards molecular oxygen has been demonstrated using the techniques of X-ray diffraction, X-ray absorption, photoemission and infrared spectroscopy. At ambient temperature a molecular intercalation compound is formed, characterised by oxygen-rich surface and sub-surface regions. At higher temperatures oxidation to CO2 is preceded by the formation of various carbon suboxide intermediates, as reported in the literature.

引用

页码：403 / 409

页数：7

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