Carbon Dioxide as a Feedstock for the Chemical Industry. Production of Green Methanol

被引:4
|
作者
Mota, Claudio J. A. [1 ,2 ,3 ]
Monteiro, Robson S. [1 ]
Maia, Eduardo B. V. [2 ]
Pimentel, Allan F. [1 ]
Miranda, Jussara L. [1 ,3 ]
Alves, Rita M. B. [4 ]
Coutinho, Paulo L. A. [4 ]
机构
[1] Univ Fed Rio de Janeiro, Inst Quim, Ave Athos Silveira Ramos 149,CT Bloco A, BR-21941909 Rio De Janeiro, RJ, Brazil
[2] Univ Fed Rio de Janeiro, Escola Quim, BR-21941909 Rio De Janeiro, RJ, Brazil
[3] Univ Fed Rio de Janeiro, INCT Energia & Ambiente, BR-21941909 Rio De Janeiro, Brazil
[4] Braskem SA, BR-05477000 Sao Paulo, SP, Brazil
关键词
Methanol; Carbon Dioxide; CO2; Conversion; Hydrogenation; Cu and Zn catalysts;
D O I
10.5935/1984-6835.20140005
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Carbon dioxide (CO2) has a restricted use as a feedstock in the chemical industry. Its emission and accumulation in the atmosphere in great quantities have been largely associated to the greenhouse effect. Thus, the conversion of CO2 into value-added chemical products will bring on not only economical benefits but also far greater importance for the environmental stewardship. The hydrogenation of CO2 into methanol (CH3OH) is a promising route to fix CO2 in the chemical industry. The reaction can be carried out by Cu and Zn-based catalysts, which are highly selective to CH3OH formation. However, the reaction is severely affected by the thermodynamic equilibrium. Therefore, the effect of reaction temperature and pressure needs to be known in order to achieve high conversion rates of CO2 into CH3OH, thus allowing the development of feasible and highly efficient conversion processes.
引用
收藏
页码:44 / 59
页数:16
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