STEREOCHEMISTRY IN DEHYDROGENATION OF 3-ALPHA,7-ALPHA,12-ALPHA-TRIHYDROXY-5-BETA-CHOLESTAN-26-OYL COA DURING CHOLIC-ACID BIOSYNTHESIS

被引：1

作者：

YURI, M

HARA, N

FUJIMOTO, Y

KOBAYASHI, N

MORISAKI, M

HAGIWARA, C

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM,MEGURO KU,TOKYO 152,JAPAN

[2] KYORITSU COLL PHARMACEUT SCI,MINATO KU,TOKYO 105,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 20期

关键词：

D O I：

10.1039/c39940002325

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dehydrogenation reaction, catalysed by 3 alpha, 7 alpha, 12 alpha-trihydroxy-5 beta-cholestan-26-oyl CoA oxidase, is elucidated to proceed via syn-elimination of [24-pro-R]-hydrogen and 25-hydrogen.

引用

页码：2325 / 2326

页数：2

共 50 条

[1] FORMATION OF CHOLIC-ACID VIA 3-ALPHA,7-ALPHA,12-ALPHA-TRIHYDROXY-5-BETA-CHOLESTAN-26-OIC ACID IN THE DOG
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[6] IDENTIFICATION OF 3-ALPHA,7-ALPHA,12-ALPHA-TRIHYDROXY-5-BETA-CHOLESTAN-26-OIC ACID, AN INTERMEDIATE IN CHOLIC-ACID SYNTHESIS, IN THE PLASMA OF PATIENTS WITH INFANTILE REFSUMS DISEASE
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