NEODYMIUM-DOPED SR-5(PO4)(3)F AND SR-5(VO4)(3)F

被引：15
|
作者：
CORKER, DL [1 ]
机构：
[1] UNIV CENT FLORIDA,CREOL,ORLANDO,FL
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷
关键词：
D O I：
10.1107/S0108270194006906
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Neodymium-doped Sr-5(PO4)(3)F [neodymium strontium fluoride phosphate, (Nd,Sr)(5)(PO4)(3)F] and neodymium-doped Sr-5(VO4)(3)F [neodymium strontium fluoride vanadate, (Nd,Sr)(5)(VO4)(3)F] crystallize in space group P6(3)/m and are isostructural with calcium fluorophosphate, Ca-5(PO4)(3)F. There are two different Sr sites in Sr-5(XO(4))(3)F, denoted Sr(1) and Sr(2). Using single-crystal X-ray diffraction the two structures were refined to R factors of 2.3 and 2.2%, respectively, showing that Nd is present at both Sr sites in (Sr,Nd)(5)(VO4)(3)F but only at the Sr(2) site in (Sr,Nd)(5)(PO4)(3)F.
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收藏
页码：549 / 551
页数：3
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