MAGNETOSTRUCTURAL CORRELATIONS IN DIMERIC COPPER(II) CARBOXYLATES

被引:0
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作者
OHBA, S
KATO, M
TOKII, T
MUTO, Y
STEWARD, OW
机构
[1] SAGA UNIV,FAC SCI & ENGN,DEPT CHEM,SAGA 840,JAPAN
[2] DUQUESNE UNIV,DEPT CHEM,PITTSBURGH,PA 15282
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
For dimeric copper(II) carboxylates, the most important factor determining the strength of the spin superexchange interactions is the electronic structure of the carboxylato bridge. It also has been revealed that the trigonal bipyramidal deformation of the coordination geometry around the copper atoms, and the bending of the carboxylato bridge decrease the antiferromagnetic interactions.
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页码:695 / 704
页数:10
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