SURPRISING FORMATION OF A CARBORANE-SUBSTITUTED DIGALLANE

被引：37
|
作者：
SAXENA, AK
ZHANG, HM
MAGUIRE, JA
HOSMANE, NS
COWLEY, AH
机构：
[1] SO METHODIST UNIV,DEPT CHEM,DALLAS,TX 75275
[2] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 03期
关键词：
CARBORANES; DIGALLANES; GALLIUM COMPOUNDS;
D O I：
10.1002/anie.199503321
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A very short GaGa bond, stabilized by carborane moieties, is present in the digallane 1, which is air‐ and moisture‐sensitive, and soluble in both polar and nonpolar organic solvents. The coordination of each Ga atom to the respective C2B3 carborane face is “slip distorted”. • = H, □ = SiMe3. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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页码：332 / 334
页数：3
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