EFFICIENT DIRECT AROMATIC AMINATION BY HYDRAZOIC ACID IN THE PRESENCE OF BOTH TRIFLUOROMETHANESULFONIC ACID AND TRIFLUOROACETIC-ACID

被引：11
|
作者：
TAKEUCHI, H
ADACHI, T
NISHIGUCHI, H
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 21期
关键词：
D O I：
10.1039/c39910001524
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of hydrazoic acid with aromatic compounds in the presence of both trifluoromethanesulphonic acid and trifluoroacetic acid efficiently gave primary arylamines by a concerted process involving nucleophilic attack of the aromatic compound on the conjugate acid of the azide and elimination of N2 from the conjugate acid.
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页码：1524 / 1525
页数：2
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