AN ANALYSIS OF THE SPECIFIC-HEAT CAPACITY OF LIQUID AU-SN ALLOY BASED ON THE IDEAL-ASSOCIATED SOLUTION MODEL

被引:6
|
作者
WASAI, K [1 ]
KANO, M [1 ]
MUKAI, K [1 ]
机构
[1] SCI UNIV TOKYO,FAC SCI,DEPT PHYS,SHINJUKU KU,TOKYO 162,JAPAN
关键词
ACTIVITY; ASSOCIATED COMPOUNDS; AU-SN LIQUID ALLOY; HEAT OF DISSOCIATION; HEAT OF MIXING; IDEAL ASSOCIATED SOLUTION; SPECIFIC HEAT CAPACITY;
D O I
10.1007/BF01438868
中图分类号
O414.1 [热力学];
学科分类号
摘要
The specific heat capacity of Au-Sn liquid alloy was analyzed using the ideal associated solution model assuming associated compounds Au-3 Sn, AuSn, and AuSn2. Based on this model, all of the specific heat capacity, heat of mixing, and activity are described over a wide temperature range. Further, it became clear that the summation of mole numbers of the species in the liquid alloy shows a minium at the stoichiometric composition of Au-3 Sn, which implies that the liquid is the most ordered at this composition.
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页码:831 / 839
页数:9
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