CRITERION OF MULTIPLICITY OF STEADY-STATES AND THE EXPLICIT EXPRESSION FOR BIFURCATION SET IN THE SIMPLEST MODEL OF A CATALYTIC REACTION WITH AN ARBITRARY ISOTHERM

被引：2

作者：

MYSHLYAVTSEV, AV

SAMDANCHAP, RT

机构：

[1] Tuvinian Complex Department of Sibirian Branch of Russian, Academy of Sciences, Kyzyl

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1994年 / 53卷 / 02期

关键词：

D O I：

10.1007/BF02073030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The following criterion of multiplicity of steady states (m.s.s.) for the simplest model of an open heterogeneous catalytic system (monomolecular isomerization in CSTR) with an arbitrary isotherm was obtained in this paper: theta + d theta/d<(mu)over bar> > 1 An explicit expression for bifurcation set in the plane of two generalized parameters of the system has been derived. It was described the connection between first-order phase transitions and m.s.s.

引用

页码：269 / 276

页数：8

共 5 条

[1] ON THE MULTIPLICITY CRITERION FOR STEADY-STATES IN CATALYTIC REACTIONS
FEDOTOV, VK
ALEKSEEV, BV
KOLTSOV, NI
KIPERMAN, SL
REACTION KINETICS AND CATALYSIS LETTERS, 1984, 26 (1-2): : 25 - 29
[2] MULTIPLICITY CRITERION FOR STEADY-STATES OF CATALYTIC REACTIONS IN NONISOTHERMAL CONDITIONS
KOLTSOV, NI
FEDOTOV, VK
ALEKSEYEV, BV
DOKLADY AKADEMII NAUK SSSR, 1991, 317 (02): : 401 - 406
[3] A MULTIPLICITY CRITERION FOR STEADY-STATES IN SINGLE-ROUTE CATALYTIC REACTIONS
KOLTSOV, NI
FEDOTOV, VK
ALEXEEV, BV
DOKLADY AKADEMII NAUK SSSR, 1988, 302 (01): : 126 - 131
[4] 3-PHASE MULTICOMPARTMENT MODEL FOR FLUIDIZED-BED CATALYTIC REACTORS - AUTOTHERMICITY AND MULTIPLICITY OF STEADY-STATES
TABIS, B
ESSEKKAT, A
CHEMICAL ENGINEERING SCIENCE, 1992, 47 (02) : 407 - 419
[5] MULTIPLICITY OF STEADY-STATES AND AUTOOSCILLATIONS IN AN OPEN REACTION CATALIZED BY PHOSPHOFRUCTOKINASE FROM ESCHERICHIA-COLI - A QUANTITATIVE MODEL
MALKOVA, IA
POPOVA, SV
SELKOV, EE
BIOFIZIKA, 1980, 25 (03): : 503 - 507

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