A STUDY OF TRINUCLEAR IRON(III) O-PHTHALATES

被引：5

作者：

HANZEL, D

BILINSKI, H

HIMDAN, TA

MILJAK, M

VANCINA, V

机构：

[1] RUDJER BOSKOVIC INST, Zagreb, YUGOSLAVIA

[2] INST PHYS, Zagreb, YUGOSLAVIA

[3] HIGH SCH PRINTING, Zagreb, YUGOSLAVIA

来源：

HYPERFINE INTERACTIONS | 1990年 / 53卷 / 1-4期

关键词：

D O I：

10.1007/BF02101063

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Mössbauer data as well as infrared and magnetic susceptibility results indicate that Fe(III)-phthalates are high spin ferric complexes with a combination of trinuclear oxo-bridged and monomer structures. Values obtained for the isomer shift and quadrupole splitting parameters suggest that different counter ions, such as OH, NO3, and Na, leave the Fe(III) ions in two very distorted octahedral arrangements, although they scarcely affect the electron densities at the iron nuclei. © 1990 J.C. Baltzer AG, Scientific Publishing Company.

引用

页码：339 / 343

页数：5

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