A COMPARATIVE-STUDY OF TEMPERATURE BROADENING OF SPECTRAL HOLES BURNT IN ABSORPTION-BANDS OF MONOMERS AND J-AGGREGATES OF A THIACARBOCYANINE DYE

被引:3
|
作者
DROBIZHEV, MA [1 ]
NOVIKOV, AV [1 ]
SAPOZHNIKOV, MN [1 ]
VARNAVSKY, OP [1 ]
VITUKHNOVSKY, AG [1 ]
USHOMIRSKY, MN [1 ]
机构
[1] INFO PHOTO LTD,MOSCOW 117421,RUSSIA
关键词
D O I
10.1016/0009-2614(95)00074-E
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
J-aggregates and monomers of a thiacarbocyanine derivative are investigated in glassy matrices by spectral hole burning. The temperature dependence (at T 4.6-20 K) of the width of the hole burnt in the absorption band of aggregates differs qualitatively from that of the hole in the absorption band of monomers. The hole width for J-aggregates does not depend on temperature below 9 K and is equal to 3.3 cm(-1). This residual hole width is suggested to be determined by exciton-phonon scattering with phonon emission.
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页码:425 / 430
页数:6
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